Ozonolysis of Methyl 3β-Hydroxyolean-9(11),12(13)-Dien-30-Oate

Autor:	L. R. Mikhailova, Leonid V. Spirikhin, A. S. Budaev, Baltina Lidiya A
Rok vydání:	2016
Předmět:	NMR spectra database 010404 medicinal & biomolecular chemistry Ozonolysis Triterpenoid 010405 organic chemistry Chemistry Organic chemistry Plant Science General Chemistry 01 natural sciences General Biochemistry Genetics and Molecular Biology 0104 chemical sciences
Zdroj:	Chemistry of Natural Compounds. 52:448-451
ISSN:	1573-8388 0009-3130
DOI:	10.1007/s10600-016-1670-z
Popis:	Ozonolysis of methyl 3β-hydroxyolean-9(11),12(13)-dien-30-oate at –60°C in CH2Cl2–MeOH followed by reduction of the ozonolysis products by dimethylsulfide formed methyl esters of 3β-hydroxy-18βH-olean-9(11),14(15)-dien-12β-methoxy-30-oic and -olean-9(11)-en-12-oxo-30-oic acids and stereoisomeric 12α, β-hydroxy derivatives of olean-9(11),14(15)-dien-12β-methoxy-30-oic acid. The structures of the oxidation products were established using CH-correlation NMR spectra.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5143694f6a560d9fa4e27723841b0a12 https://doi.org/10.1007/s10600-016-1670-z Zobrazit plný text záznamu Plný text ve formátu PDF