Chemical Reactions in Lithium Sulfur Dioxide Cells Discharged at High Rates and Temperatures
| Autor: | D. L. Demuth, W. L. Bowden, R. W. Holmes, L. Chow |
|---|---|
| Rok vydání: | 1984 |
| Předmět: |
Renewable Energy
Sustainability and the Environment Analytical chemistry Infrared spectroscopy chemistry.chemical_element Condensed Matter Physics Alkali metal Electrochemistry Chemical reaction Surfaces Coatings and Films Electronic Optical and Magnetic Materials Electrochemical cell Chemical kinetics chemistry.chemical_compound chemistry Materials Chemistry Lithium Sulfur dioxide |
| Zdroj: | Journal of The Electrochemical Society. 131:229-234 |
| ISSN: | 1945-7111 0013-4651 |
| DOI: | 10.1149/1.2115554 |
| Popis: | The discharge capacity of Li/SO/sub 2/ cells was examined at high current and temperatures. D cells rated at 8 Ah delivered over 7 Ah at 5A current and 55/sup 0/C, while cells discharged at 72/sup 0/C gave 7 Ah at 3A. The cells were analyzed for residual lithium and sulfur dioxide. Spent cathodes were analyzed by infrared spectroscopy. A parasitic reaction was found in which Li/sub 2/S/sub 2/O/sub 6/ and S were formed, presumably by reaction of Li/sub 2/S/sub 2/O/sub 4/ with SO/sub 2/. This reaction became noticeable only under extreme combination of high rate and temperature. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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