High performance and reusable SERS substrates using Ag/ZnO heterostructure on periodic silicon nanotube substrate

Autor: Yi-Chen Lai, Bo-Wei Shih, Feng-Yu Tsai, Chun-Hway Hsueh, Hsin-Chia Ho
Rok vydání: 2018
Předmět:
Zdroj: Applied Surface Science. 439:852-858
ISSN: 0169-4332
DOI: 10.1016/j.apsusc.2018.01.092
Popis: Surface-enhanced Raman scattering (SERS) substrate with a higher surface area, enhanced light harvesting, multiple hot spots and strong electromagnetic field enhancements would exhibit enhanced Raman signals. Herein, the Ag nanoparticle/ZnO nanowire heterostructure decorated periodic silicon nanotube (Ag@ZnO@SiNT) substrate was proposed and fabricated. The proposed structure employed as SERS-active substrate was examined, and the results showed both the high performance in terms of high sensitivity and good reproducibility. Furthermore, the Ag@ZnO@SiNT substrate demonstrated the self-cleaning performance through the photocatalytic degradation of probed molecules upon UV-irradiation. The results showed that the proposed nanostructure had high performance, good reproducibility and reusability, and it is a promising SERS-active substrate for molecular sensing and cleaning.
Databáze: OpenAIRE