Synthesis and reactions of hydroxydiamantanones

Autor:	Sergei D. Isaev, Luděk Vodička, J. Burkhard, Josef Janků
Rok vydání:	1984
Předmět:	chemistry.chemical_classification Ketone Carboxylation Chemistry Stereochemistry General Chemistry
Zdroj:	Collection of Czechoslovak Chemical Communications. 49:1900-1906
ISSN:	1212-6950 0010-0765
Popis:	Diamantanone can be oxidized with chromium trioxide in acetic acid solutions to give 11-hydroxy-, 1-hydroxy-, and 9-hydroxy-3-diamantanone as the major products and two diamantanonediones of unelucidated structure as by-products. The Koch-Haaf carboxylation of hydroxydiamantanones results in the formation of the corresponding oxodiamantanecarboxylic acids. Reacted with 100% HNO3, diamantanone transforms into 9-(3-diamantanoyl) nitrate. Reactions of the carbonyl groups of these compounds with H2NOSO2OH lead to hydrazidiamantane derivatives, which oxidized with CrO3 provide the azidiamantane derivatives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::50e8249c822951a2965a08c15f4c833f https://doi.org/10.1135/cccc19841900 Zobrazit plný text záznamu