Synthesis and reactions of hydroxydiamantanones
Autor: | Sergei D. Isaev, Luděk Vodička, J. Burkhard, Josef Janků |
---|---|
Rok vydání: | 1984 |
Předmět: | |
Zdroj: | Collection of Czechoslovak Chemical Communications. 49:1900-1906 |
ISSN: | 1212-6950 0010-0765 |
Popis: | Diamantanone can be oxidized with chromium trioxide in acetic acid solutions to give 11-hydroxy-, 1-hydroxy-, and 9-hydroxy-3-diamantanone as the major products and two diamantanonediones of unelucidated structure as by-products. The Koch-Haaf carboxylation of hydroxydiamantanones results in the formation of the corresponding oxodiamantanecarboxylic acids. Reacted with 100% HNO3, diamantanone transforms into 9-(3-diamantanoyl) nitrate. Reactions of the carbonyl groups of these compounds with H2NOSO2OH lead to hydrazidiamantane derivatives, which oxidized with CrO3 provide the azidiamantane derivatives. |
Databáze: | OpenAIRE |
Externí odkaz: |