Autor:	T. V. Karmanova, B. D. Berezin, T. V. Gromova, A. S. Semeikin
Rok vydání:	2002
Předmět:	General Chemical Engineering Inorganic chemistry Kinetics chemistry.chemical_element General Chemistry Zinc Medicinal chemistry Toluene Acetic acid chemistry.chemical_compound Reaction rate constant chemistry Pyridine Molecule Pyrrole
Zdroj:	Russian Journal of Coordination Chemistry. 28:834-838
ISSN:	1070-3284
Popis:	Rate constants of zinc acetate complexation with 2,7,12,17-tetrabromo-5,10,15,20-tetraphenylporphine in toluene, pyridine, or acetic acid following the reaction H2TPP(β-Br)4 + Zn(Ac)2 → ZnTPP(β-Br)4 + 2HAc are determined at four temperatures in the interval of 298–328 K, and the activation energies and entropies are calculated. The effect of bromo-substitution in pyrrole fragments of a tetraphenylporphine molecule on the complexation kinetics and mechanism is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::50c4b9b3e9fb58e81235544c80383fbe https://doi.org/10.1023/a:1021626127175 Zobrazit plný text záznamu Full text from SpringerLink