| Popis: |
In this study, the effect of operating parameters and the co-existing ions on the phosphate removal during the ferrous iron oxidation was investigated. Results showed that with the increase of DO and [Fe (II)]0, the final phosphate removal rate both increased. But with increasing of pH, the final phosphate removal rate firstly increased and then decreased when the pH was higher than 8.0. The co-existing ions affected the final removal rate significantly, and the kinetics of phosphate removal followed the pseudo-first-order kinetic model. The corresponding kobs trends for the cation followed the order of Cu2+>Mn2+>Zn2+>NH4+-N. The presence of Cu2+ promoted the phosphate removal significantly. Compared with the control, , the time required to achieve 40 % phosphate removal rate, at the condition of 0.5 mg/L Cu2+, reduced from 60 min to 10 s. However, the selective anions inhibited the phosphate removal, due to the formation of Fe-anions complexes. The effect of selective anions on the phosphate removal rate constant decreased in the order of SO42->Cl-> NO3-. |
