Isotope Effects in the Reaction of H+(H2O)2/D+(D2O)2 with Acetone/Dimethylsulfoxide
Autor: | Yoko Kawai, Hiromi Nakai, Satoru Yamaguchi, Yoshiki Okada, Kazuo Takeuchi, Yusuke Yamauchi |
---|---|
Rok vydání: | 2005 |
Předmět: | |
Zdroj: | Journal of the Mass Spectrometry Society of Japan. 53:305-308 |
ISSN: | 1880-4225 1340-8097 |
DOI: | 10.5702/massspec.53.305 |
Popis: | We investigated isotope effects in the reactions of protonated water dimer ions H+(H2O)2/D+(D2O)2 with acetone and dimethylsulfoxide (DMSO) using a guided ion beam apparatus. The reaction cross section, σr, of H+(H2O)2 with acetone was found to be slightly larger than that of D+(D2O)2 at low collision energies |
Databáze: | OpenAIRE |
Externí odkaz: |