ESR study of reactivity of the complex (η2-C60)Os(CO)(PPh3)2(CNBut) toward free radicals

Autor:	Yu. N. Novikov, E. V. Martynova, R. G. Gasanov, M. V. Tsikalova
Rok vydání:	2008
Předmět:	Fullerene Chemistry Competitive kinetics Radical General Chemistry Photochemistry Medicinal chemistry Fullerene molecule law.invention Reaction rate constant law Reactivity (chemistry) Spectroscopy Electron paramagnetic resonance
Zdroj:	Russian Chemical Bulletin. 57:309-315
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-008-0048-1
Popis:	Addition of the ·P(O)(OPri)2, Me·, Et·, ·But, and Cl3C· radicals to the (ν2-C60)Os(CO)-(PPh3)2(CNBut) complex (1) was studied by ESR spectroscopy. The spectral parameters of the spin-adducts of these radicals with complex 1 were determined. The predominant direction of the attack by the ·P(O)(OPri)2, ·But, and Cl3C· radicals are the cis-1 and cis-2 bonds of the fullerene molecule. The stability of the spin-adducts depends substantially on the nature of the added radical. The addition rate constants of the ·P(O)(OPri)2, ·But, and Cl3C· radicals to complex 1 and the dimerization rate constants for these spin-adducts were determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::504fe4b6cc12dacb782cad98c2341bbc https://doi.org/10.1007/s11172-008-0048-1 Zobrazit plný text záznamu Full text from SpringerLink