Chlorination studies of unsaturated materials in nonpolar media—VI

Autor:	J.L. Kartch, M.L. Poutsma
Rok vydání:	1966
Předmět:	Cyclohexane Organic Chemistry Ionic bonding chemistry.chemical_element Chain transfer Fraction (chemistry) Hydrogen atom abstraction Biochemistry Medicinal chemistry chemistry.chemical_compound chemistry Drug Discovery Chlorine Organic chemistry Hydrogen chloride
Zdroj:	Tetrahedron. 22:2167-2176
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)82137-2
Popis:	Treatment of neat 1-butyne with chlorine at −9° led to a negligible ionic or spontaneously-initiated free-radical reaction compared to 1-butene. However, photo-initiation led to production of seven products in the ratios shown: trans-1,2-dichloro-1-butene (Ia, 85–90%), cis-1,2-dichloro-1-butene (IIa, 2–3%), 3-chloro-1-butyne (VI, 3–5%), 1-chloro-1,2-butadiene (VII, 1%), 4-chloro-1-butyne (VIII, 2–3%), cis-1-chloro-1-butene (IV, 1–3%) and 2-chloro-1-butene (III
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5035c1360663330684bcdd9b0f306e02 https://doi.org/10.1016/s0040-4020(01)82137-2 Zobrazit plný text záznamu