Laboratory production of zirconium carbide compacts for use in inert matrix fuels
| Autor: | Elwyn Roberts, Gokul Vasudevamurthy, Thad Adams, Travis W. Knight |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
Exothermic reaction
Nuclear and High Energy Physics Zirconium Materials science Zirconium dioxide Metallurgy Sintering chemistry.chemical_element Combustion Endothermic process Carbide Zirconium carbide chemistry.chemical_compound Nuclear Energy and Engineering chemistry Chemical engineering General Materials Science |
| Zdroj: | Journal of Nuclear Materials. 374:241-247 |
| ISSN: | 0022-3115 |
| Popis: | Zirconium carbide is being actively considered for use as an inert matrix material in composite nuclear fuel for gas-cooled fast reactors. ZrC can be produced either by the endothermic carbothermal reduction of zirconium dioxide or by the direct exothermic reaction of pure zirconium and graphite powder mixtures. The exothermic reaction is classified as combustion synthesis or self heating synthesis. Experiments were conducted to demonstrate the combustion synthesis reaction of zirconium and graphite powders and measure the ignition and adiabatic temperatures. The heat released during this short reaction time was sufficient only to partially sinter the compacts to less than 40% theoretical density. Subsequently, compacts of ZrC were similarly produced by combustion synthesis followed by a short, high temperature hold at 2440 °C to relieve residual stresses in the compacts following the rapid reaction sintering. External pressures of up to 5.2 MPa were used as an additional driving force for sintering. The effects of reactant particle size and degree of uniaxial pressing on the product density and porosity were also studied. Higher densities in the fabricated compacts were noted for higher uniaxial pressures irrespective of powder size. Also, smaller powder sizes produced compacts up to 92% TD, while larger particle sizes produced compacts up to 84% TD for the same pressure. The compacts were characterized based on composition, microstructure, and density/porosity. Results of the different experiments are presented. |
| Databáze: | OpenAIRE |
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