A theoretical and experimental study on meridional–facial isomerization of tris(quinolin-8-olate)aluminum (Alq3)

Autor:	H. Ebina, Yoshihiro Koide, Keiko Komori-Orisaku, Izumi Iwakura
Rok vydání:	2014
Předmět:	Inorganic Chemistry Tris chemistry.chemical_compound Stereospecificity Chemistry Aluminium Physical chemistry chemistry.chemical_element Density functional theory Zonal and meridional Photochemistry Isomerization Ion
Zdroj:	Dalton Trans.. 43:12824-12827
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c4dt01121j
Popis:	The rationale behind the stereospecific synthesis of a facial isomer of tris(quinolin-8-olate)aluminum (Alq3) is studied by density functional theory (DFT) calculations, which predict the favourable influence of an H3O+ ion on the distribution ratio between a meridional and a thermodynamically unstable facial isomer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4fef4e51091183cce653a84856ea1b4c https://doi.org/10.1039/c4dt01121j Zobrazit plný text záznamu