Drastic ring transformation reactions of fused bicyclic rings to bridged bicyclic rings

Autor:	Toshiko Eki, Hiroshi Suemune, Shinji Nagumo, Kiyoshi Sakai, Takayoshi Yamamoto
Rok vydání:	1992
Předmět:	Diketone Octanone Bicyclic molecule Chemistry Organic Chemistry Cyclohexanone Ring (chemistry) Biochemistry Medicinal chemistry chemistry.chemical_compound Drug Discovery Aldol condensation Octene Derivative (chemistry)
Zdroj:	Tetrahedron. 48:4517-4524
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)81224-2
Popis:	By treatment with BF 3 -etheratelethylene glycol, cyclohexanone with a carbonyl function at the 2′-(or 3′-) position of γ-side chain underwent novel ring transformation to afford five- (or six-) membered rings, and the fused bicyclic rings (bicyclo[3.3.0]octanone skeleton) were readily converted to bridged bicyclic rings (bicyclo[3.2.1]octene derivative).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4fe84acac83fe6b896d3ef31d341c07b https://doi.org/10.1016/s0040-4020(01)81224-2 Zobrazit plný text záznamu