Time-resolved spectroscopy in81Br2: gyroscopic and hyperfine predissociation

Autor: F Peeters, J. Van Craen, Henri Eisendrath
Rok vydání: 1989
Předmět:
Zdroj: Journal of Physics B: Atomic, Molecular and Optical Physics. 22:2541-2554
ISSN: 1361-6455
0953-4075
DOI: 10.1088/0953-4075/22/16/012
Popis: Lifetime measurements of a number of (v, J) rovibronic levels are performed in pure isotopic 81Br2. The gyroscopic and hyperfine predissociation parameters are obtained by mono- and multi-exponential analysis of the fluorescence decay. A comparison of the two methods is made. The results obtained by multi-exponential analysis are also compared with those obtained by intensity measurements on single hyperfine components in molecular beam experiments. The results do not reveal the same string J dependence of the predissociation parameters.
Databáze: OpenAIRE