Reactions of selected methyl tin (IV) and-germanium(IV) halides in anhydrous HF, HSO3F and HSO3CF3
| Autor: | Friedhelm Aubke, S. T. Tomic, S.P. Mallela, H.A. Carter, S. Lee, S. Karunanithy, John R. Sams |
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| Rok vydání: | 1989 |
| Předmět: |
Fluorosulfuric acid
Denticity Chemistry Organic Chemistry Inorganic chemistry Halide chemistry.chemical_element Germanium Nuclear magnetic resonance spectroscopy Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Sulfonate Anhydrous Environmental Chemistry Physical and Theoretical Chemistry Tin |
| Zdroj: | Journal of Fluorine Chemistry. 44:309-328 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/s0022-1139(00)83948-2 |
| Popis: | Acidolysis in HSO 3 F or HSO 3 CF 3 of either tetramethylgermane or trimethylchlorogermane leads, depending on reaction conditions, to (CH 3 ) 3 GeSO 3 X or (CH 3 ) 2 Ge(SO 3 X) 2 with X = F or CF 3 . All compounds are obtained as colorless liquids with tetracoordinated germanium and monodentate sulfonate groups. The compounds are characterized by 19 F - and 1 H - NMR and vibrational spectra. All but (CH 3 ) 2 Ge(SO 3 F) 2 are obtained in analytically pure form. Dimethyltin(IV) fluoride is found to act as an ampholyte in anhydrous HF as evidenced by the isolation of Li 2 [(CH 3 ) 2 SnF 4 ], K[(CH 3 ) 2 SnF 3 ] and a material of the composition (CH 3 ) 2 SnTaF 7 . Vibrational and 119 Sn Mossbauer spectra are reported and discussed. Tin is found to be hexacoordinated in all compounds with linear or nearly linear C - Sn - C groups. |
| Databáze: | OpenAIRE |
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