Additional Data on the Synthesis and Properties of Chiral 1,2-Bis(phosphetano)benzenes

Autor: Angela Marinetti, Louis Ricard, Jean‐Pierre Genet, Sébastien Jus
Rok vydání: 2000
Předmět:
Zdroj: Tetrahedron. 56:95-100
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(99)00777-2
Popis: The synthesis of chiral, C 2 -symmetric 1,2-bis(phosphetano)benzenes 2 has been extended to the benzyl-substituted derivative 2c (R=CH 2 Ph). Stable ruthenium and palladium complexes containing ligands 2 have been isolated. X-Ray diffraction studies have been performed on the monoborane adduct of 2a (R= i -Pr) and on a palladium(II) complex of 2b (R=Me).
Databáze: OpenAIRE