Additional Data on the Synthesis and Properties of Chiral 1,2-Bis(phosphetano)benzenes
Autor: | Angela Marinetti, Louis Ricard, Jean‐Pierre Genet, Sébastien Jus |
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Rok vydání: | 2000 |
Předmět: | |
Zdroj: | Tetrahedron. 56:95-100 |
ISSN: | 0040-4020 |
DOI: | 10.1016/s0040-4020(99)00777-2 |
Popis: | The synthesis of chiral, C 2 -symmetric 1,2-bis(phosphetano)benzenes 2 has been extended to the benzyl-substituted derivative 2c (R=CH 2 Ph). Stable ruthenium and palladium complexes containing ligands 2 have been isolated. X-Ray diffraction studies have been performed on the monoborane adduct of 2a (R= i -Pr) and on a palladium(II) complex of 2b (R=Me). |
Databáze: | OpenAIRE |
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