A photoelectron and energy-loss spectroscopy study of Ti and its interaction with H2, O2, N2 and NH3
| Autor: | Steven L. Bernasek, B.M. Biwer |
|---|---|
| Rok vydání: | 1986 |
| Předmět: |
Auger electron spectroscopy
Chemistry Analytical chemistry chemistry.chemical_element Surfaces and Interfaces Condensed Matter Physics medicine.disease_cause Electron spectroscopy Surfaces Coatings and Films X-ray photoelectron spectroscopy Materials Chemistry medicine Crystallite Spectroscopy Tin Electronic band structure Ultraviolet |
| Zdroj: | Surface Science. 167:207-230 |
| ISSN: | 0039-6028 |
| DOI: | 10.1016/0039-6028(86)90795-8 |
| Popis: | A unified electron spectroscopic study of polycrystalline Ti and its interaction with H2, O2, N2, and NH3 are described. Auger electron spectroscopy (AES), electron energy-loss spectroscopy (ELS), ultraviolet and X-ray photoelectron spectroscopy (UPS and XPS) are combined to provide detailed information about the electronic structure of the titanium surface and its interaction with these adsorbates. X-ray and ultraviolet photoelectron spectra and electron energy-loss spectra are presented for the clean titanium surface, and following exposure to H2, O2, N2 and NH3. Spectral assignments are provided in each case. The electron spectra of oxygen exposed Ti and nitrogen sputtered Ti are quite similar, and are interpreted with reference to band structure calculations for TiO and TiN. Electron spectroscopy indicates essentially complete dissociative adsorption of NH3 on the clean titanium surface. |
| Databáze: | OpenAIRE |
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