Primary Li / SOCl2 Cells: XI . Reduction Mechanism in a Supporting Electrolyte
| Autor: | W. L. Bowden, A. N. Dey |
|---|---|
| Rok vydání: | 1980 |
| Předmět: |
Reaction mechanism
Primary (chemistry) Renewable Energy Sustainability and the Environment Chemistry Supporting electrolyte Inorganic chemistry Electrolyte Condensed Matter Physics Electrochemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials Coulometry Materials Chemistry Cyclic voltammetry Spectroscopy |
| Zdroj: | Journal of The Electrochemical Society. 127:1419-1426 |
| ISSN: | 1945-7111 0013-4651 |
| DOI: | 10.1149/1.2129923 |
| Popis: | The electrochemical reduction of has been investigated in organic solvents with supporting electrolytes, using cyclic voltammetry, coulometry, and UV‐VIS spectroscopy. An overall 2.0F reduction was observed. Comparison of voltammograms of , S, and with those of reduced solutions demonstrated that intermediate species are formed in the reduction of . These intermediates decompose slowly to form S and . Reaction mechanisms consistent with these findings are discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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