A novel palladium catalyst for the synthesis of hydrogen peroxide from carbon monoxide, water and oxygen

Autor:	Rino D'Aloisio, Daniele Bianchi, Rossella Bortolo, Marco Ricci
Rok vydání:	1999
Předmět:	inorganic chemicals Denticity Process Chemistry and Technology Phenanthroline Inorganic chemistry chemistry.chemical_element Oxygen Catalysis Turnover number chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Hydrogen peroxide Carbon monoxide Palladium
Zdroj:	Journal of Molecular Catalysis A: Chemical. 150:87-94
ISSN:	1381-1169
Popis:	The synthesis of hydrogen peroxide from carbon monoxide, water and oxygen in a biphasic system using palladium complexes with bidentate nitrogen ligands as catalysts was investigated. After testing a series of phenanthroline derivatives, 2,9-dimethyl-4,7-diphenylphenanthroline (8) was selected as the most efficient ligand. The palladium complex with ligand 8 showed high stability and catalytic activity (turnover number up to 600 moles of hydrogen peroxide per mole of palladium per hour) and, on the basis of a preliminary study, carried out in continuous operation mode, it appears a promising catalyst for the development of an industrial process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4f75fa9d26b09993b7b70c6ceacb6c47 https://doi.org/10.1016/s1381-1169(99)00218-6 Zobrazit plný text záznamu Full Text from ScienceDirect