Hexakis[μ2-4-(N-n-butylimino)pentan-2-onato]trimagnesium(II)

Autor: T. S. Ouattara, Ray J. Butcher, Jason S. Matthews
Rok vydání: 2005
Předmět:
Zdroj: Acta Crystallographica Section E Structure Reports Online. 61:m2598-m2600
ISSN: 1600-5368
DOI: 10.1107/s1600536805033830
Popis: The title compound, [Mg3(C9H16NO)6], represents a trimeric complex with all Mg atoms having octa­hedral coordination. The central Mg atom occupies a special position on a crystallographic inversion centre and is coordinated by six O atoms [Mg—O = 2.069 (2), 2.083 (2) and 2.072 (2) A], all of which have bridging functions. Each of the peripheral Mg atoms is coordinated by three bridging O atoms [Mg—O = 2.090 (2), 2.086 (2) and 2.095 (2) A] and three terminal N atoms of the butyl­imino groups [Mg—N = 2.206 (2), 2.202 (2) and 2.196 (2) A].
Databáze: OpenAIRE