ChemInform Abstract: Diastereoselective Formation of Pyruvylated Glycosides from Partly Protected Sugars and Methyl Pyruvate

Autor: Elisabeth Eckhardt, Gerhard Herold, Thomas Ziegler
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 23
ISSN: 0931-7597
DOI: 10.1002/chin.199252268
Popis: Various partly protected sugars ( gluco-, manno-, and galactopyranosides ) were acetalized with methyl pyruvate in moderate to good yield with BF 3 -etherate as the condensing reagent. Thus, (1-methoxycarbonyl)ethylidene glycosides were obtained diastereoselectivity.
Databáze: OpenAIRE