Surface Acidity and Photocatalytic Activity of Nb2O5/TiO2 Photocatalysts

Autor: S. Soled, H. Cui, Aaron Wold, Kirby Dwight
Rok vydání: 1995
Předmět:
Zdroj: Journal of Solid State Chemistry. 115:187-191
ISSN: 0022-4596
DOI: 10.1006/jssc.1995.1118
Popis: Samples of Nb2O5/TiO2 mixed oxide powders were prepared by the incipient wetness method. The photocatalytic activities of TiO2 based catalysts were evaluated by the degradation of 1,4-dichlorobenzene (DCB). The addition of Nb2O5 to TiO2 greatly increased its photocatalytic activity and also increased the catalyst's surface acidity, as determined by the n-butylamine titration method. A correlation between the maximum photocatalytic activity and the number and strength of acid sites were observed. Consequently, the same structural feature that enhances the adsorption of n-butylamine appears to promote the catalytic activity.
Databáze: OpenAIRE