An Effective and Stable HfP/SiO2 Catalyst for the Production of Furfural from Xylan
| Autor: | Donghui Pan, Siquan Xu, Yuanfeng Wu, Lijing Gao, Hui Yuan, Guomin Xiao, Yuan Chen, Ningxin Wu, Jingdeng Fan |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Chemistry Phosphide Xylan (coating) General Chemistry Polymer 010402 general chemistry Furfural 01 natural sciences Catalysis Hydrothermal circulation 0104 chemical sciences chemistry.chemical_compound Yield (chemistry) Humin Nuclear chemistry |
| Zdroj: | Catalysis Letters. 150:1121-1127 |
| ISSN: | 1572-879X 1011-372X |
| DOI: | 10.1007/s10562-019-02994-2 |
| Popis: | Silica-supported hafinum phosphide (HfP/SiO2) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/SiO2 catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/SiO2 catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the water(NaCl)/THF biphasic system. There was no significant decrease in the performance of the HfP/SiO2 catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/SiO2 catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. |
| Databáze: | OpenAIRE |
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