SIZE VARIATION OF Tb-DOPED Gd2O3 NANOPARTICLES STUDIED BY X-RAY EXCITED LUMINESCENCE AND DIFFRACTION

Autor: Yun-Liang Soo, Y. W. Yang, S. W. Huang, V. Chhabra, R. N. Bhargava, Y. H. Kao, L. J. Lai, B. Kulkami, J. V. D. Veliadis
Rok vydání: 2001
Předmět:
Zdroj: Modern Physics Letters B. 15:205-211
ISSN: 1793-6640
0217-9849
DOI: 10.1142/s021798490100163x
Popis: Post-fabrication heat treatment has been found as an effective means for controlling the size distribution of Tb-doped Gd 2 O 3 nanoparticles. Variations in the electronic structure and structural order of these doped quantum dots are investigated by using the techniques of X-ray excited luminiscence and diffraction. From room temperature to 1000°C X-ray powder diffraction of this nanoparticle system shows a three-stage transition from featureless data to that of the bulk crystalline structure with increasing particle size. However, substantial changes found in the X-ray excited luminescence are not directly related to the crystalline structure of the nanoparticles. These observations also indicate that bulk-like crystalline phase of the quantum dot material is not a necessary condition for generating the X-ray induced optical effects which are useful for some technological applications.
Databáze: OpenAIRE