Free Energy, Enthalpy and Entropy Changes of the Ag (I) Complexes of Some ω-Aminocarboxylic Acids

Autor:	Z. Eeckhaut, L.C. Van Poucke, G. F. Thiers, M. A. Herman
Rok vydání:	2010
Předmět:	Chemistry Enthalpy Complex formation Physical chemistry Thermodynamics General Chemistry Temperature coefficient Entropy (order and disorder)
Zdroj:	Bulletin des Sociétés Chimiques Belges. 79:611-616
ISSN:	0037-9646
DOI:	10.1002/bscb.19700791103
Popis:	The acidity constants of the ω-aminocarboxylic acids with n = 1,2,3,4,5 and the stability constants of the Ag(I) complexes of the corresponding aminocarboxylates were determined at 0°, 15° and 40°C in o.5 M KNO3. From this and the same data at 25°, reported previously, the free energy, enthalpy and entropy changes involved in complex formation were calculated using the temperature coefficient method. The same thermodynamic functions were also obtained from calorimetric data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4f1759c6ed049924cd25b0aad0e16722 https://doi.org/10.1002/bscb.19700791103 Zobrazit plný text záznamu