Comparative study of B10H12 (NH3)2 and B10H12 (NEt3)2 by the methods of X-ray spectroscopy

Autor:	V. D. Yumatov, L. N. Mazalov, E. A. Il'inchik, G. F. Khudorozhko, Vladimir Volkov
Rok vydání:	1985
Předmět:	Steric effects Crystallography Delocalized electron Valence (chemistry) Atomic orbital Chemical bond chemistry Computational chemistry chemistry.chemical_element General Chemistry Spectroscopy Boron Acceptor
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 34:2079-2085
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00963238
Popis:	1. In the complexes B10H12L2 the B10H12 fragment behaves as a delocalized electron-deficient acceptor. 2. The movement of the valence MO's of the boron atoms in the B10H12 fragment to deeper positions in the case of an NH3 ligand may be caused by an interaction involving the d orbitals of the nitrogen atom. Another explanation for the difference in the ligand-skeleton chemical bonding may be the steric effects associated with the geometry of N(Et)3.
Databáze:	OpenAIRE
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