Determination of gel time and gel point of epoxy-amine thermosets by in-situ near infrared spectroscopy
| Autor: | Xiaoyu Li, Hongfu Yuan, Chunfeng Song, Yanan Cao, Zhi-qiang Zhu, Xiting Sun |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Polymers and Plastics 010401 analytical chemistry Organic Chemistry Near-infrared spectroscopy Analytical chemistry Thermosetting polymer Wavelet transform 02 engineering and technology Epoxy 021001 nanoscience & nanotechnology 01 natural sciences Spectral line 0104 chemical sciences Wavelet visual_art visual_art.visual_art_medium 0210 nano-technology Spectroscopy Curing (chemistry) |
| Zdroj: | Polymer Testing. 72:416-422 |
| ISSN: | 0142-9418 |
| Popis: | A method of near-infrared spectroscopy combined with wavelet transform was proposed to determine in-situ the gel time and gel point of epoxy resin simultaneously. The reconstructed spectra of the low-frequency wavelet coefficients were used for determination of gel time, and the reconstructed spectra of some detail coefficients which are dominated by chemical information for determination of epoxy conversion. In-situ determination of gel point has been achieved using evolutionary near infrared spectra of epoxy curing. The accuracy of gel point achived to 0.01. Compared with the traditional determination method of gel point, in which TMA and DSC are respectively used for gel time and conversion, this method not only can determine in-situ gel time and conversion degree simultaneously, and remarkably improve accuracy of the gel point result but also is of low cost, and fast and easy to operate. |
| Databáze: | OpenAIRE |
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