Effects of isomeric alcohols on the phase behavior and solubilization of the microemulsion systems formed by anionic surfactants
| Autor: | Zai-mei Zhang, Jian-Jun Lu, Xiao-nan Xue, Yan Li, Jinling Chai |
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| Rok vydání: | 2010 |
| Předmět: |
organic chemicals
Sodium Butanol Inorganic chemistry chemistry.chemical_element Surfaces and Interfaces equipment and supplies carbohydrates (lipids) Hildebrand solubility parameter chemistry.chemical_compound Colloid and Surface Chemistry Sulfonate chemistry bacteria lipids (amino acids peptides and proteins) Microemulsion Physical and Theoretical Chemistry Solubility Sodium dodecyl sulfate Octane |
| Zdroj: | Colloid Journal. 72:183-187 |
| ISSN: | 1608-3067 1061-933X |
| Popis: | The middle-phase ɛ-β fishlike phase diagrams of the pseudoquaternary microemulsion systems sodium dodecyl sulfate (sodium dodecyl sulfonate, sodium dodecyl benzene sulfonate)/1-butanol (2-butanol, t-butanol)/n-octane/brine (5% NaCl) were plotted. The effect of three isomeric alcohols (1-butanol, 2-butanol, and t-butanol) on the phase behavior and solubilization was investigated. From the ɛ-β fishlike phase diagram, the composition of the interfacial layer, the solubilities of alcohols and the solubilization ability (the solubility parameter SP*, and the middle-phase volume fraction ϕ) of the microemulsion systems were calculated and discussed. The alcohol content in the interfacial layer and the solubilities of alcohols are in the order: 1-butanol < 2-butanol < t-butanol, but the solubilization ability is in the inverse order. |
| Databáze: | OpenAIRE |
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