Three atropisomers of biphenyl: twist by tunable para substituents

Autor:	Ramesh Karupnaswamy, Prabusankar Ganesan
Rok vydání:	2018
Předmět:	Biphenyl Atropisomer 010405 organic chemistry Stereochemistry Substituent General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Para position chemistry.chemical_compound chemistry Molecule Imidazole Twist Selone
Zdroj:	Journal of Chemical Sciences. 130
ISSN:	0973-7103 0974-3626
DOI:	10.1007/s12039-018-1482-8
Popis:	The geometrical twist of aryl-aryl bond in biphenyl by weakly coordinating anion and selone at the para position has not been clear so far. We report here the synthesis and investigation into the diverse structural properties of biphenyl with weakly coordinating biphenyl imidazolium salts and neutral imidazole selone that exhibit three atropisomers of biphenyl. The approaches underline the diversity of the effects of para substituent with dynamic nature at biphenyl molecule. SYNOPSIS The synthesis and investigation into the diverse structural properties of three atropisomers of biphenyl tuned by para substituted weakly coordinating imidazolium salts and neutral imidazole selone are reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4ebbe9f67af10dbd60e93a1bf09902c9 https://doi.org/10.1007/s12039-018-1482-8 Zobrazit plný text záznamu Full text from SpringerLink