Cyclopropylmethoxycarbene: A kinetic limit on the 1,2-carbon migration

Autor:	Eun G. Jang, Karsten Krogh-Jespersen, Marek Włostowski, Robert A. Moss, Hong Fan
Rok vydání:	1992
Předmět:	Organic Chemistry Intermolecular force Substituent chemistry.chemical_element Ether Photochemistry chemistry.chemical_compound Reaction rate constant chemistry Intramolecular force Methanol Physical and Theoretical Chemistry Carbon Carbene
Zdroj:	Journal of Physical Organic Chemistry. 5:104-107
ISSN:	1099-1395 0894-3230
DOI:	10.1002/poc.610050207
Popis:	Cyclopropylmethoxycarbene undergoes ambiphilic-nucleophilic intermolecular reaction with alkenes and methanol, but its intramolecular chemistry (1,2-carbon migration) is suppressed (k < 3 × 103 s−1) by the α-methoxy substituent.
Databáze:	OpenAIRE
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