Stabilization of one-dimensional conducting materials by carbonyl ligands. Crystal and molecular structure of tricarbonylchloroiridium

Autor:	A. H. Reis, S. W. Peterson, V. S. Hagley
Rok vydání:	1977
Předmět:	Crystallography Colloid and Surface Chemistry Chemistry Lattice (order) Valency Halide Molecule General Chemistry Crystal structure Biochemistry Catalysis Stoichiometry
Zdroj:	Journal of the American Chemical Society. 99:4184-4186
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00454a061
Popis:	The characterization of Ir(CO)/sub 3/Cl, a one-dimensional highly conducting stoichiometric material in which chains containing short Ir metal-metal bonds of 2.844(1) A are stabilized without mixed valency or charge transfer to interstitial anions within the lattice, is reported. (LK)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4eb61e5165cc0ac640f365a566c968a1 https://doi.org/10.1021/ja00454a061 Zobrazit plný text záznamu