Two copper(II) coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and dicarboxylate ligands

Autor:	Yang Lei, Gao Xiao‐Na, Li Hui, Tang Yu‐Peng, MA Hui‐Xuan, Zhang Xiao, Sun Hong, Wang Gao‐Feng, Sun Shu‐Wen
Rok vydání:	2017
Předmět:	chemistry.chemical_classification Chemistry Polymer chemistry chemistry.chemical_element General Chemistry Polymer 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Copper 0104 chemical sciences
Zdroj:	Zeitschrift für Naturforschung B. 72:257-261
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-2016-0225
Popis:	Two new copper(II) complexes, {[Cu(bipmo)(npa)]} n (1) and {[Cu(bipmo)(pa)]} n (2) (bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of neutral metal aromatic carboxylate layers, which are pillared by the weak interactions to generate 3D architectures. The topological structures of 1 and 2 are uninodal nets based on 4-connected nodes with the Schläfli symbol of (65·8).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4e9d4564539ea3c14c3db991e870848a https://doi.org/10.1515/znb-2016-0225 Zobrazit plný text záznamu Plný text ve formátu PDF