NMR study of reactions of organyltrichlorophosphonium hexachlorophosphorates with triethylamine

Autor:	Lyudmila I. Larina, V. G. Rozinov, T. N. Komarova
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Primary (chemistry) chemistry Group (periodic table) Alkoxy group Organic chemistry General Chemistry Phosphonium 31p nmr spectroscopy Nuclear magnetic resonance spectroscopy Medicinal chemistry Triethylamine
Zdroj:	Russian Chemical Bulletin. 64:732-737
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-015-0927-1
Popis:	The reactions of trichloro(2-ethoxyethenyl)phosphonium and trichloro(styryl)phosphonium hexachlorophosphorates with triethylamine were studied by 1H, 13C, and 31P NMR spectroscopy. It was shown that phosphonyl chlorides are the primary products of the reactions. The presence of the alkoxy group in hexachlorophosphorate results in the oxidation of the PCl2 group to form phosphonyl chlorides. Diphosphorylated oxaphosphinines were synthesized.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4e90998838bc727f4ffba1ae14d4b0c8 https://doi.org/10.1007/s11172-015-0927-1 Zobrazit plný text záznamu Full text from SpringerLink