RADIATION-INDUCED CYCLOREVERSION OF INDENE CYCLOBUTANE DIMERS INn-BUTYL CHLORIDE BY A CHAIN REACTION MECHANISM

Autor: SakuraiHiroshi, TakamukuSetsuo, MajimaTetsuro, PacChyongjin
Rok vydání: 1979
Předmět:
Zdroj: Chemistry Letters. 8:1149-1152
ISSN: 1348-0715
0366-7022
DOI: 10.1246/cl.1979.1149
Popis: The cycloreversion of trans,syn- and cis,syn-indene dimers (I and II) occurred upon γ-radiation of n-butyl chloride solutions. The effects of additives and high G values for formation of indene demonstrated that the cycloreversion proceeds by means of a chain reaction mechanism involving cation radicals as chain carriers.
Databáze: OpenAIRE