Synthesis, structure and thermal decomposition of cycloalkanone enamine peroxides

Autor:	E. K. Starostin, Andrei V. Lalov, Victor N. Khrustalev, Mikhail Yu. Antipin
Rok vydání:	2009
Předmět:	chemistry.chemical_compound chemistry Morpholine Thermal decomposition Organic chemistry Cyclohexanone General Chemistry Nuclear magnetic resonance spectroscopy Enamine
Zdroj:	Mendeleev Communications. 19:334-336
ISSN:	0959-9436
DOI:	10.1016/j.mencom.2009.11.014
Popis:	Reactions of cycloalkanone enamines with H2O2 gave bis(1-morpholinocyclopent-1-yl)- and bis(1-morpholinocyclohex-1-yl)-peroxides, which were studied by NMR spectroscopy and X-ray diffraction. Thermolysis of bis(1-morpholinocyclohex-1-yl)-peroxide in n-hexane resulted in two major products, viz., cyclohexanone and morpholine.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4e6b4e17ed60b898f2ba1aad4104de6a https://doi.org/10.1016/j.mencom.2009.11.014 Zobrazit plný text záznamu Full Text from ScienceDirect