A rapid route to medium to large ring lactones via the thermolysis of dispiro-1,2,4-trioxane derivatives

Autor:	Kevin J. McCullough, Bernadette Kerr, Ahsanul Haq
Rok vydání:	1993
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry 1 2 4-Trioxane Thermal decomposition Molecular Medicine Organic chemistry Decane Ring (chemistry) Pyrolysis Lactone
Zdroj:	Journal of the Chemical Society, Chemical Communications. :1076
ISSN:	0022-4936
Popis:	Dispiro-1,2,4-trioxane derivatives 3, on thermolysis in decane at 190 °C, afford either oxalactones 4, or ketolactones 5, or mixtures of both as the predominant ring-expansion products depending on the respective natures of the dispiro substituents.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4e3d2bec3cbf2312e73c46882a99470d https://doi.org/10.1039/c39930001076 Zobrazit plný text záznamu