N,N-Dimethylformamide-stabilised palladium nanoparticles combined with bathophenanthroline as catalyst for transfer vinylation of alcohols from vinyl ether
| Autor: | Yasushi Obora, Masato Nakatsuji, Takeyuki Suzuki, Kazuki Tabaru, Satoshi Itoh |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
inorganic chemicals
Chemistry organic chemicals Organic Chemistry technology industry and agriculture Nanoparticle Palladium nanoparticles Vinyl ether Photochemistry Biochemistry Catalysis Dynamic light scattering Transmission electron microscopy medicine N dimethylformamide Physical and Theoretical Chemistry medicine.drug |
| Zdroj: | Organic & Biomolecular Chemistry. 19:3384-3388 |
| ISSN: | 1477-0539 1477-0520 |
| Popis: | We report N,N-dimethylformamide-stabilised Pd nanoparticle (Pd NP)-catalysed transfer vinylation of alcohols from vinyl ether. Pd NPs combined with bathophenanthroline exhibited high catalytic activity. This reaction proceeded with low catalyst loading and the catalyst remained effective even after many rounds of recycling. The observation of the catalyst using transmission electron microscopy and dynamic light scattering implied no deleterious aggregation of Pd NPs. |
| Databáze: | OpenAIRE |
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