Syntheses, crystal structures, and fluorescent properties of three coordination polymers with 5-sulfoisophthalic acid anion and 4-phenylpyridine

Autor:	Zhou Chichi, Xiu-Qing Zhang, Chen Fangmin, Yan Li
Rok vydání:	2021
Předmět:	chemistry.chemical_classification chemistry 5-sulfoisophthalic acid Acid anion Polymer chemistry General Chemistry Polymer Crystal structure Fluorescence Ion
Zdroj:	Journal of Chemical Research. 45:1052-1058
ISSN:	2047-6507 1747-5198
DOI:	10.1177/17475198211055089
Popis:	Three coordination polymers—{[Ag2(SIP)(4-pp)]·[Ag(4-pp)2]·H2O}n, [Pb4(SIP)2( μ3-OH)2(H2O)2]n, and {[Zn2(SIP)2(4-pp)4][Zn(4-pp)2(H2O)4]·4H2O}n (SIP = 5-sulfoisophthalic acid anion, 4-pp = 4-phenylpyridine)—are constructed under hydrothermal or solvothermal conditions using sodium m-phthalate 5-sulfonate (NaH2SIP) and 4-phenylpyridine as ligands. The structures of the three complexes are determined by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analyses, Fourier-transform infrared analysis, and photoluminescence. The fluorescent properties of the complexes in the solid state are investigated at room temperature, and the results indicate that they all show photoluminescent properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4db27278bc86cecf9f2fa5037a94a572 https://doi.org/10.1177/17475198211055089 Zobrazit plný text záznamu Plný text ve formátu PDF