Structure analysis of [Be(NCS) 2 (C 5 H 5 N) 2 ]
| Autor: | W. Hanay, M. Noltemeyer, H. Böhland, Anton Meller, Hans-Georg Schmidt |
|---|---|
| Rok vydání: | 1998 |
| Předmět: |
Thiocyanate
010405 organic chemistry Chemistry Hydrogen bond Crystal structure 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences 3. Good health Crystallography chemistry.chemical_compound Yield (chemistry) Pyridine Tetrahedron Orthorhombic crystal system Single crystal |
| Zdroj: | Fresenius' Journal of Analytical Chemistry. 361:725-728 |
| ISSN: | 1432-1130 0937-0633 |
| DOI: | 10.1007/s002160051005 |
| Popis: | [Be(NCS)2(C5H5N)2] was prepared and characterized by chemical analysis, FT-IR-analysis, and single crystal X-ray structure analysis. The crystals are orthorhombic with a = 829.30(10) pm, b = 1292.1(2) pm, c = 1313.40(10) pm, space group Pnma. Z = 4. The structure is built up from tetrahedra. Hydrogen bonding between the S-atom of one Be-N-bonded thiocyanate and 1.3-H-atoms of pyridine ligands yield a three dimensional network consisting of folded sheets. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink