Alkoxycarbonylation of Industrially Relevant Anilines Using Zn4O(O2CCH3)6 as Catalyst

Autor:	Anton Vidal-Ferran, Elisenda Reixach, Stefan Wershofen, Robert M. Haak
Rok vydání:	2012
Předmět:	chemistry.chemical_classification Chemistry Stereochemistry General Chemical Engineering Reagent Organic chemistry General Chemistry Ring (chemistry) Environmentally friendly Industrial and Manufacturing Engineering Alkyl Catalysis Electronic properties
Zdroj:	Industrial & Engineering Chemistry Research. 51:16165-16170
ISSN:	1520-5045 0888-5885
DOI:	10.1021/ie301315k
Popis:	An efficient procedure is presented for the alkoxycarbonylation of industrially important amines using environmentally friendly alkyl carbonates as reagents and Zn4O(OAc)6 as catalyst. Aromatic amines in particular (thirteen examples) consistently give high yields (up to 98%), regardless of the electronic properties of the substituents or the ring substitution pattern.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4da52bf99fae52a5f663d860488b3931 https://doi.org/10.1021/ie301315k Zobrazit plný text záznamu