Z,E-isomerism of fluorinated mono- and diacylhydrazines
Autor: | I. D. Kalikhman, P. V. Makerov, E. N. Medvedeva, T. I. Yushmanova, V. A. Lopyrev |
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Rok vydání: | 1979 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:1760-1764 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00951018 |
Popis: | It was established by the1H and19F NMR method that the insertion of fluorine atoms in the acyl radical of mono- and diacylmethylhydrazines has a substantial effect on the population of the rotamers, without noticeably changing the activation energy of the E-Z isomerization. |
Databáze: | OpenAIRE |
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