Z,E-isomerism of fluorinated mono- and diacylhydrazines

Autor: I. D. Kalikhman, P. V. Makerov, E. N. Medvedeva, T. I. Yushmanova, V. A. Lopyrev
Rok vydání: 1979
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:1760-1764
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00951018
Popis: It was established by the1H and19F NMR method that the insertion of fluorine atoms in the acyl radical of mono- and diacylmethylhydrazines has a substantial effect on the population of the rotamers, without noticeably changing the activation energy of the E-Z isomerization.
Databáze: OpenAIRE