Pyrolytic decomposition of solid propellants

Autor:	R. A. Fifer, R. A. Pesce-Rodriguez
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Propellant General Chemical Engineering Analytical chemistry Plasticizer General Chemistry Polymer Decomposition Product distribution law.invention Ignition system chemistry law Pyrolytic carbon Pyrolysis
Zdroj:	Pure and Applied Chemistry. 65:317-323
ISSN:	1365-3075 0033-4545
DOI:	10.1351/pac199365020317
Popis:	has been used to examine the pyrolysis product distributions of a composite propellant formulation series. The series was formulated with the oxidizers HMX and RDX, the polymers GAP, HTPB, BAMO/AMMO, and BAMOTTHF, and the plasticizers BlTN and TMETN. Trends in product distribution as a function of formulation, as well as correlations between radiative ignition times and pyrolysis products were identified. The most noteworthy correlations observed were between the amounts of permanent gases and amides produced and goho-go ignition time. In general, pyrolysis product distribution were found to be most strongly affected by the presence and type of plasticizer. Pyrolysis - gas chromatography - Fourier transform infrared (P-GC-FTIR) spectroscopy
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4d8ee88708a18efe7c0450ef6b12b09b https://doi.org/10.1351/pac199365020317 Zobrazit plný text záznamu