Modification of the theory of a three-dimensional filling of micropores

Autor:	M.M. Dubinin, V. V. Serpinskii, Alexander V. Neimark
Rok vydání:	1992
Předmět:	Thermodynamics Langmuir adsorption model General Chemistry Microporous material chemistry.chemical_compound symbols.namesake Adsorption Volume (thermodynamics) chemistry Computational chemistry Automotive Engineering medicine Compressibility symbols Benzene Activated carbon medicine.drug
Zdroj:	Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:5-9
ISSN:	1573-9171 1063-5211
Popis:	Compressibility of the adsorbate has been taken into account in calculating the maximum adsorption in micropores. On this basis, an equation has been derived for improvement of the theory of three-dimensional filling of micropores in application to the calculation of micropore volume by the Dubinin-Radushkevich equation. Evaluations for the case of benzene adsorption on activated carbons at ∼20°C have shown that the accounting for adsorbate compressibility leads to corrections of the Dubinin-Radushkevich theory amounting to approximately 10%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4d8a19cf99ae75505256a5b88acc0faa https://doi.org/10.1007/bf00863901 Zobrazit plný text záznamu Full text from SpringerLink