Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)

Autor: P.C.M Gubbens, Glen A. Stewart, S. J. Harker
Rok vydání: 2000
Předmět:
Zdroj: Journal of Alloys and Compounds. 307:70-76
ISSN: 0925-8388
DOI: 10.1016/s0925-8388(00)00840-9
Popis: The magnetic ordering and crystal field interactions of the Pnma phases of both Tm2BaCoO5 and Tm2BaNiO5 are investigated by 169Tm Mossbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm2BaCuO5. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm2BaCoO5) and 4.85(5) K (Tm2BaNiO5), the order being induced by the transition metal. For Tm2BaNiO5 an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice.
Databáze: OpenAIRE