Magnetic order and crystal fields in the Pnma phases of Tm2BaTO5 (T=Co and Ni)
Autor: | P.C.M Gubbens, Glen A. Stewart, S. J. Harker |
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Rok vydání: | 2000 |
Předmět: | |
Zdroj: | Journal of Alloys and Compounds. 307:70-76 |
ISSN: | 0925-8388 |
DOI: | 10.1016/s0925-8388(00)00840-9 |
Popis: | The magnetic ordering and crystal field interactions of the Pnma phases of both Tm2BaCoO5 and Tm2BaNiO5 are investigated by 169Tm Mossbauer spectroscopy and the temperature-dependent hyperfine interactions are compared with those obtained elsewhere for Tm2BaCuO5. The Pnma phases are shown to order magnetically at temperatures of 3.5(2) K (Tm2BaCoO5) and 4.85(5) K (Tm2BaNiO5), the order being induced by the transition metal. For Tm2BaNiO5 an additional first-order transition observed at T≤1.4 K is identified with the independent magnetic order of the thulium sub-lattice. |
Databáze: | OpenAIRE |
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