An Experimental Study of the Smectic A-Smectic C Transitions in Monolayer, Partially Bilayer and Bilayer Systems

Autor: S. Krishna Prasad, M. E. Neubert, Gerd Heppke, S. Chandrasekhar, V. N. Raja, D. S. Shankar Rao
Rok vydání: 1994
Předmět:
Zdroj: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 238:241-247
ISSN: 1058-725X
Popis: The smectic A-smectic C (A-C) transition in several compounds has been shown to be mean-field-like (MF) with a substantial tricritical crossover effect. However, a simple MF behaviour, i.e., with negligible tricritical influence, had not been reported till recently. The heat capacity measurements of the MIT group in two compounds exhibiting the bilayer A2−C2 transition revealed such a behaviour. It is of interest to investigate whether a simple MF behaviour can be observed for partially bilayer Ad−Cd and monolayer A1−C1 transitions also. We report the first systematic order parameter measurements in the vicinity of the A2−C2, Ad−Cd and A1−C1 transitions. The data analysed in terms of power law and extended mean field expressions provide clear evidence of a simple MF behaviour in all three cases. The significance of this result is discussed.
Databáze: OpenAIRE