Easy access to the voaketone ring system
Autor: | Arto Tolvanen, David Din Belle, Mauri Lounasmaa |
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Rok vydání: | 1998 |
Předmět: | |
Zdroj: | Tetrahedron. 54:4673-4678 |
ISSN: | 0040-4020 |
Popis: | Intramolecular aldol condensation of ketoaldehyde 8 affords three new compounds: enone 9 , hydroxyketone 10 , and enone 11 . Enone 9 possesses the ring system of (−)-voaketone ( 1 ), which is a skeletal rearrangement product of the indole alkaloid (−)-voacangine. |
Databáze: | OpenAIRE |
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