Deep state in the bandgap and photoluminescence of Zn1−xMnxO
Autor: | V. V. Menshenin, G. A. Emelchenko, V. N. Churmanov, Victor I. Sokolov, N. B. Gruzdev |
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Rok vydání: | 2021 |
Předmět: |
010302 applied physics
Materials science Photoluminescence Physics and Astronomy (miscellaneous) Band gap General Physics and Astronomy Atmospheric temperature range Condensed Matter::Mesoscopic Systems and Quantum Hall Effect Antibonding molecular orbital 01 natural sciences Condensed Matter::Materials Science Dipole Impurity Ionization 0103 physical sciences Atomic physics 010306 general physics Excitation |
Zdroj: | Low Temperature Physics. 47:32-38 |
ISSN: | 1090-6517 1063-777X |
Popis: | The impurity absorption in Zn1−xMnxO is formed by dipole allowed p-s transitions from deep antibonding p-d hybrid (pdh) state to the conduction band. In this paper, photoluminescence of Zn1−xMnxO single crystals was investigated in the temperature range of 7–340 K at laser excitation with the energy of 3.06 eV. Intensive photoluminescence band was observed in the energy region of 2.40–1.6 eV with the maximum at the energy of 2.17 eV. The energy of the impurity center ionization 2.35 eV was determined in this paper. The analysis of photoluminescence band form, and also close coincidence of its headline and impurity band edge allow us to interprete this band as a result of radiative dipole allowed s-p transitions from the conduction band to impurity pdh level. |
Databáze: | OpenAIRE |
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