Electrochemical Properties of LiNi1/3Co1/3Mn1/3O2 Powders Prepared by Internal Combustion Type Spray Pyrolysis

Autor: Kenichi Myoujin, Takanori Tsuzuki, Masao Uede, Takayuki Kodera, Izumi Mukoyama, Takashi Ogihara
Rok vydání: 2008
Předmět:
Zdroj: Key Engineering Materials. 388:89-92
ISSN: 1662-9795
DOI: 10.4028/www.scientific.net/kem.388.89
Popis: LiNi1/3Co1/3Mn1/3O2 precursor powders were successfully prepared by internal combustion type spray pyrolysis. The production capacity of precursor powders was about 1 kg/h when the solution concentration was 0.5 mol/dm3. Particle size, morphology and crystal phase of LiNi1/3Co1/3Mn1/3O2 powders were characterized by XRD and SEM. XRD showed that a layered rock salt structure with a R3m space group was formed by calcination at 750 °C for 10 h. SEM showed that hollow powders with a particle size of 6 μm and irregular morphology were obtained. The discharge capacity of LiNi1/3Co1/3Mn1/3O2 was 130 mAh/g, which showed good cycle performance.
Databáze: OpenAIRE