Catalytic Activity of Supported Rhodium(I) Complex for the Carbonylation of Nitrobenzene: Mechanism for Carbamate Formation

Autor:	Minserk Cheong, Dae Won Kim, Jin Hyung Kim, Deb Kumar Mukherjee, Hoon Sik Kim
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Carbamate medicine.medical_treatment Dimer chemistry.chemical_element General Chemistry Polymer Isocyanate Medicinal chemistry Rhodium Catalysis Nitrobenzene chemistry.chemical_compound chemistry medicine Organic chemistry Carbonylation
Zdroj:	Bulletin of the Korean Chemical Society. 31:1621-1627
ISSN:	0253-2964
DOI:	10.5012/bkcs.2010.31.6.1621
Popis:	] (P-S; polymer anchored sali -cylic acid) toward the reductive carbonylation of nitrobenzene in DMF medium has been reported. Use of basic coca -talysts in the reaction medium enhanced the percentage of more useful phenyl carbamates. Spectroscopic studies indicate that the reaction proceeds through a dimer species [Rh(HS)(CO)(C(O)OCH
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4d52774d403b8e4c54b45ef593a1cb00 https://doi.org/10.5012/bkcs.2010.31.6.1621 Zobrazit plný text záznamu