Carbonylation with CO2 and Phosphorus Electrophiles: A Convenient Method for the Synthesis of 2-Oxazolidinones from 1,2-Amino Alcohols

Autor:	Jairo Paz, Carlos Pérez-Balado, Beatriz Iglesias, Luis Muñoz
Rok vydání:	2009
Předmět:	chemistry.chemical_classification chemistry Base (chemistry) Phosphorus Organic Chemistry Electrophile chemistry.chemical_element Organic chemistry Carbonylation
Zdroj:	Synlett. 2009:395-398
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0028-1087531
Popis:	2-Oxazolidinones were prepared in good yields from 1,2-amino alcohols and CO 2 in the presence of tetramethyl-phenylguanidine (PhTMG) as a base and a variety of phosphorus electrophiles under mild conditions. This procedure is advantageous over previous methodologies and relies on a novel carbonylation procedure that utilizes nontoxic CO 2 and phosphorus electrophiles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4d505d73fdabddf465a91335c9aad1e9 https://doi.org/10.1055/s-0028-1087531 Zobrazit plný text záznamu