Absolute infrared band strength measurement of the ClO radical by Fourier transform infrared spectroscopy
| Autor: | Valerie I. Lang, Randall R. Friedl, Stanley P. Sander |
|---|---|
| Rok vydání: | 1988 |
| Předmět: |
Materials science
Infrared Analytical chemistry chemistry.chemical_element Infrared spectroscopy Rotational–vibrational spectroscopy Atomic and Molecular Physics and Optics Molecular electronic transition Spectral line symbols.namesake Nuclear magnetic resonance Fourier transform chemistry symbols Physical and Theoretical Chemistry Fourier transform infrared spectroscopy Spectroscopy Helium |
| Zdroj: | Journal of Molecular Spectroscopy. 132:89-103 |
| ISSN: | 0022-2852 |
| DOI: | 10.1016/0022-2852(88)90061-6 |
| Popis: | High-resolution (0.005/cm) FTIR spectra of the X2Pi(i)-X2Pi(i) (1-0) rovibrational bands of (C-35)(O-16) and (Cl-37)(O-16) were obtained in 1 torr of helium carrier gas. After measuring the strengths of approximately 830 individual IR lines from several spectra, a total band strength of 13.1 + or - 1.1/sq cm atm and a first Herman-Wallis coefficient of (4.12 + or - 0.62) x 10 to the -3rd were determined. |
| Databáze: | OpenAIRE |
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